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Your group must be set so that members can add and approve members. That setting can be adjusted by visiting your group on facebook and adding /edit to the end of the url
Then selecting the option for members to be able to add and approve members.
It is advisable to also set your group so that new posts must be approved by an admin. that is the last option on the /edit page that you just visited.
I will be requesting to join your group so that I can add members. Please Accept